2011年，我室低维物理与化学研究部王官武教授研究组与日合作在CHEMICAL COMMUNICATIONS上发表题为Manganese(III) acetate-mediated radical reaction of [60]fullerene with phosphonate esters affording unprecedented separable singly-bonded [60]fullerene dimers的论文。

Source: CHEMICAL COMMUNICATIONS Volume: 47 Issue: 21 Pages: 6111-6113 Published: 2011
Wang GW (Wang, Guan-Wu)1,2, Wang CZ (Wang, Cong-Zhou)1,2, Zhu SE (Zhu, San-E)1,2, Murata Y (Murata, Yasujiro)3
Addresses:
1. Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Joint Lab Green Synthet Chem, Hefei 230026, Anhui Peoples R China
2. Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui Peoples R China
3. Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
E-mail Addresses: gwang@ustc.edu.cn, yasujiro@scl.kyoto-u.ac.jp

Reprint Address: Wang, GW (reprint author), Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Joint Lab Green Synthet Chem, Hefei 230026, Anhui Peoples R China

Abstract: Radical reaction of [60]fullerene with phosphonate esters mediated by manganese(III) acetate in chlorobenzene afforded singly-bonded fullerene dimers, of which the individual meso and racemic isomers could be unexpectedly separated out for the first time.