2011年，我室汪志勇杜江峰教授研究组合作在CHEMICAL COMMUNICATIONS上发表题为Direct electrochemical imidation of aliphatic amines via anodic oxidation的论文。

Source: CHEMICAL COMMUNICATIONS Volume: 47 Issue: 19 Pages: 5488-5490 Published: 2011
Zhang L (Zhang, Li)1,2, Su JH (Su, Ji-Hu)3, Wang SJ (Wang, Sujing)3, Wan CF (Wan, Changfeng)1,2, Zha ZG (Zha, Zhenggen)1,2, Du JF (Du, Jiangfeng)3, Wang ZY (Wang, Zhiyong)1,2
Addresses:
1. Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Joint Lab Green Synthet Chem, Hefei 230026, Peoples R China
2. Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
3. Univ Sci & Technol China, Dept Modern Phys, Hefei 230026, Peoples R China
E-mail Addresses: zgzha@ustc.edu.cn, djf@ustc.edu.cn, zwang3@ustc.edu.cn

Reprint Address: Zha, ZG (reprint author), Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Joint Lab Green Synthet Chem, Hefei 230026, Peoples R China

Abstract: Direct electrochemical synthesis of sulfonyl amidines from aliphatic amines and sulfonyl azides was realized with good to excellent yields. Traditional tertiary amine substrates were broadened to secondary and primary amines. The reaction intermediates were observed and a reaction mechanism was proposed and discussed.