近日，我室纳米材料与化学研究部谢毅教授研究组在CHEMISTRY-A EUROPEAN JOURNAL上发表题为New-Phased Metastable V2O3 Porous Urchinlike Micronanostructures: Facile Synthesis and Application in Aqueous Lithium Ion Batteries的论文。

Source: CHEMISTRY-A EUROPEAN JOURNAL Volume: 17 Issue: 1 Pages: 384-391 Published: 2011

Xu Y (Xu, Yang)1, Zheng L (Zheng, Lei)1, Wu C (Wu, Changzheng)1, Qi F (Qi, Fei)2, Xie Y (Xie, Yi)1
Addresses:
1. Univ Sci & Technol China, Dept Nanomat & Nanochem, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui Peoples R China
2. Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230026, Anhui Peoples R China
E-mail Addresses: yxie@ustc.edu.cn

Reprint Address: Xie, Y (reprint author), Univ Sci & Technol China, Dept Nanomat & Nanochem, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui Peoples R China

Abstract:
New-phased metastable V2O3 porous urchinlike micronanostructures were first fabricated on a large scale by a simple top-down strategy of pyrolyzing a vanadyl ethylene glycolated precursor in the absence of any templates or matrices. The pyrolysis mechanism was clearly revealed by synchrotron vacuum ultraviolet (VUV) photoionization mass spectra for the first time. The new-phased metastable V2O3 exhibits a body-centered cubic bixbyite structure and shows structural evolution from metastable cubic symmetry to thermodynamically stable rhombohedral symmetry V2O3 (R) above 510 degrees C. Furthermore, the prepared V2O3 porous urchinlike micronanostructures, as anode materials in agueous lithium ion batteries, exhibit improved electrochemical properties with relatively high first discharge capacity and better cycle retention relative to thermodynamically stable V2O3 (R), which is derived from its unique microscopic crystal structure and macroscopic 3D framework with rigid morphology, porous structure, and high specific surface area.