徐允河


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姓  名:

徐允河

地  址:

安徽省合肥市包河区96号中国科学技术大学

邮  编:

230026

电  话:

18256049969

电  邮:

xyh0709@ustc.edu.cn

主  页:

https://chem.ustc.edu.cn/2012/1029/c2473a17168/page.htm




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 教育与科研经历

1999.9-2003.7

学士, 青岛大学

2003.9-2006.7

硕士, 南开大学

2006.9-2010.9

博士, 新加坡南洋理工大学

2010.9-2012.2

研究助理,新加坡南洋理工大学

2012.2-至今

副教授 (博导),中国科学技术大学


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 目前研究方向

1.

金属有机催化合成

2.

有机硅合成与应用


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 代表性论文

1.

Copper-Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes
Zheng-Li Liu, Chao Yang, Qi-Yan Xue, Meng Zhao, Cui-Cui Shan, Yun-He Xu*, Teck-Peng Loh
Angew.Chem. Int.Ed. 2019, 58, 16538–16542.

2.

Macrolide Synthesis through Intramolecular Oxidative Cross-Coupling of Alkenes
Bing Jiang, Meng Zhao, Shu-Sen Li, Yun-He Xu,* Teck-Peng Loh*
Angew.Chem. Int. Ed. 2018, 57, 5555–5559.

3.

Chelation versus Non-Chelation Control in the Stereoselective Alkenyl sp2 C-H Bond Finctionalization Reaction
Qiu-Ju Liang, Chao Yang, Fei-Fan Meng, Bing Jiang, Yun-He Xu,* Teck-Peng Loh*
Angew.Chem. Int.Ed. 2017, 56, 5091 –5095.

4.

Pd-Catalyzed Intramolecular C-N Bond Cleavage, 1,4-Migration, sp(3) C-H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand
Min Wang, Xiang Zhang, Yu-Xuan Zhuang, Yun-He Xu,* Teck-Peng Loh*
J. Am. Chem. Soc. 2015, 137, 1341-1347.

5.

Stereo- and Chemoselective Cross-Coupling between Two Electron-Deficient Acrylates: An Efficient Route to (Z, E)-Muconate Derivatives
Xu-Hong Hu, Jian Zhang, Xiao-Fei Yang, Yun-He Xu,* Teck-Peng Loh*
J. Am. Chem. Soc. 2015, 137, 3169-3172.

6.

Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)‑2-Alken-4-ynoates with Silylboronate
Min Wang, Zheng-Li Liu, Xiang Zhang, Pan-Pan Tian, Yun-He Xu,* Teck-Peng Loh*
J. Am. Chem. Soc. 2015, 137, 14830–14833.

7.

Catalytically Asymmetric Synthesis of 1,3-Bis(silyl)propenes via Copper-Catalyzed Double Proto-Silylations of Polar Enynes
Fei-Fan Meng, Jia-Hao Xie, Yun-He Xu,* Teck-Peng Loh
ACS Catal. 2018, 8, 5306-5312.

8.

Copper-Catalyzed Stereo- and Enantioselective 1,4-Protosilylation of alpha,beta-Unsaturated Ketimines To Synthesize Functionalized Allylsilanes
Bing-Chao Da, Qiu-Ju Liang, Yun-Cheng Luo, Tanveer Ahmad, Yun-He Xu,* Teck-Peng Loh
ACS Catal. 2018, 8, 6239-6245.

9.

Copper-Catalyzed Silylperoxidation Reaction of α,β-Unsaturated Ketones, Esters, Amides, and Conjugated Enynes
Yun Lan, Xi-Hao Chang, Pei Fan, Cui-Cui Shan, Zi-Bai Liu, Teck-Peng Loh*, Yun-He Xu,*
ACS Catal. 2017, 7, 7120-7125.

10.

Palladium(II)-Catalyzed Stereospecific Alkenyl C–H Bond Alkylation of Allylamines with Alkyl Iodides
Yun-Cheng Luo, Chao Yang, Sheng-Qi Qiu, Qiu-Ju Liang, Yun-He Xu*, Teck-Peng Loh*
ACS Catal. 2019, 9, 4271-4276.


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