徐允河
 | 姓 名: | 徐允河 |
地 址: | 安徽省合肥市包河区96号中国科学技术大学 | |
邮 编: | 230026 | |
电 话: | 18256049969 | |
电 邮: | xyh0709@ustc.edu.cn | |
主 页: | https://chem.ustc.edu.cn/2020/1203/c2474a462602/page.htm |
| 教育与科研经历 |
1999.9-2003.7 | 学士， 青岛大学 |
2003.9-2006.7 | 硕士， 南开大学 |
2006.9-2010.7 | 博士， 新加坡南洋理工大学 |
2010.8-2012.2 | 博士后研究，新加坡南洋理工大学 |
| 目前研究方向 |
1. | 金属有机催化合成 |
2. | 有机硅合成与应用 |
| 代表性论文 |
1. | Copper-Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes Zheng-Li Liu, Chao Yang, Qi-Yan Xue, Meng Zhao, Cui-Cui Shan, Yun-He Xu*, Teck-Peng Loh Angew.Chem. Int.Ed. 2019, 58, 16538–16542. |
2. | Macrolide Synthesis through Intramolecular Oxidative Cross-Coupling of Alkenes Bing Jiang, Meng Zhao, Shu-Sen Li, Yun-He Xu,* Teck-Peng Loh* Angew.Chem. Int. Ed. 2018, 57, 5555–5559. |
3. | Chelation versus Non-Chelation Control in the Stereoselective Alkenyl sp2 C-H Bond Finctionalization Reaction Qiu-Ju Liang, Chao Yang, Fei-Fan Meng, Bing Jiang, Yun-He Xu,* Teck-Peng Loh* Angew.Chem. Int.Ed. 2017, 56, 5091 –5095. |
4. | Pd-Catalyzed Intramolecular C-N Bond Cleavage, 1,4-Migration, sp(3) C-H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand Min Wang, Xiang Zhang, Yu-Xuan Zhuang, Yun-He Xu,* Teck-Peng Loh* J. Am. Chem. Soc. 2015, 137, 1341-1347. |
5. | Stereo- and Chemoselective Cross-Coupling between Two Electron-Deficient Acrylates: An Efficient Route to (Z, E)-Muconate Derivatives Xu-Hong Hu, Jian Zhang, Xiao-Fei Yang, Yun-He Xu,* Teck-Peng Loh* J. Am. Chem. Soc. 2015, 137, 3169-3172. |
6. | Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)‑2-Alken-4-ynoates with Silylboronate Min Wang, Zheng-Li Liu, Xiang Zhang, Pan-Pan Tian, Yun-He Xu,* Teck-Peng Loh* J. Am. Chem. Soc. 2015, 137, 14830–14833. |
7. | Catalytically Asymmetric Synthesis of 1,3-Bis(silyl)propenes via Copper-Catalyzed Double Proto-Silylations of Polar Enynes Fei-Fan Meng, Jia-Hao Xie, Yun-He Xu,* Teck-Peng Loh ACS Catal. 2018, 8, 5306-5312. |
8. | Copper-Catalyzed Stereo- and Enantioselective 1,4-Protosilylation of alpha,beta-Unsaturated Ketimines To Synthesize Functionalized Allylsilanes Bing-Chao Da, Qiu-Ju Liang, Yun-Cheng Luo, Tanveer Ahmad, Yun-He Xu,* Teck-Peng Loh ACS Catal. 2018, 8, 6239-6245. |
9. | Copper-Catalyzed Silylperoxidation Reaction of α,β-Unsaturated Ketones, Esters, Amides, and Conjugated Enynes Yun Lan, Xi-Hao Chang, Pei Fan, Cui-Cui Shan, Zi-Bai Liu, Teck-Peng Loh*, Yun-He Xu,* ACS Catal. 2017, 7, 7120-7125. |
10. | Palladium(II)-Catalyzed Stereospecific Alkenyl C–H Bond Alkylation of Allylamines with Alkyl Iodides Yun-Cheng Luo, Chao Yang, Sheng-Qi Qiu, Qiu-Ju Liang, Yun-He Xu*, Teck-Peng Loh* ACS Catal. 2019, 9, 4271-4276. |
