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Substrate catalyzes on-surface reactions

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报告题目   Substrate catalyzes on-surface reactions
报告人   Dr. GAO Hongying
报告人单位   Physikalisches Institut, Westfälische Wilhelms-Universität, Wilhelm-Klemm-Straße 10, 48149 Münster (Germany)
报告时间   2017-10-30
报告地点   合肥微尺度物质科学国家实验室九楼会议室(9004)
主办单位   合肥微尺度物质科学国家实验室
报告介绍
Abstract:
  In the on-surface chemistry area, an important topic is how the surface serves for reactions. To reveal this aspect, Glaser coupling, decarboxylation, amine-coordination, Ullman coupling, domino-reaction, C-C or C-H coupling, carbene-reaction and sigma bond metathesis  were systematically investigated at various metal surfaces, which prove that the surface acts not only as a supporting surface but also a catalyst. Further, various organometallic intermediate states were observed in experiments, that help to understand how the surface atoms take part in the reactions.

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