报告题目 | Substrate catalyzes on-surface reactions |
报告人 | Dr. GAO Hongying |
报告人单位 | Physikalisches Institut, Westfälische Wilhelms-Universität, Wilhelm-Klemm-Straße 10, 48149 Münster (Germany) |
报告时间 | 2017-10-30 |
报告地点 | 合肥微尺度物质科学国家实验室九楼会议室(9004) |
主办单位 | 合肥微尺度物质科学国家实验室 |
报告介绍 | Abstract:
In the on-surface chemistry area, an important topic is how the surface serves for reactions. To reveal this aspect, Glaser coupling, decarboxylation, amine-coordination, Ullman coupling, domino-reaction, C-C or C-H coupling, carbene-reaction and sigma bond metathesis were systematically investigated at various metal surfaces, which prove that the surface acts not only as a supporting surface but also a catalyst. Further, various organometallic intermediate states were observed in experiments, that help to understand how the surface atoms take part in the reactions. |