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Chirality-Sensitive Spectroscopies of Non-Covalent Interactions

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报告题目   Chirality-Sensitive Spectroscopies of Non-Covalent Interactions
报告人   Prof. XU Yunjie
报告人单位   Department of Chemistry, University of Alberta, Canada
报告时间   2017-05-10
报告地点   合肥微尺度物质科学国家实验室九楼会议室(9004)
主办单位   合肥微尺度物质科学国家实验室
报告介绍
Abstract:
  Our research program focuses on applying and developing new spectroscopic tools to determine chirality and to establish chirality recognition models at the molecular level. Our recent rotational spectroscopic studies of clusters of 2-fluoroethanol and trifluoroethanol, two common organic solvents, highlight the importance of bifurcated H-bonds and F···F attractive interactions and their decisive roles in conformational preference. We also apply vibrational circular dichroism and Raman optical activity to probe how chiral molecules interact with each other and with solvent molecules directly in solution. Recent examples on H-bonding, dihydrogen-bonding, and halogen-bonding will be discussed. Finally, a new instrument development on coupling mass spectrometry with IR laser spectroscopy will also be described.

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