| 报告题目 | Recent Advances in the Metal Catalyzed Cycloaddition/Annulation Reactions of Donor-Acceptor Cyclopro |
| 报告人 | Prof. Michael A. Kerr |
| 报告人单位 | Department of Chemistry, Western University |
| 报告时间 | 2012-10-15 |
| 报告地点 | 合肥微尺度物质科学国家实验室一楼科技展厅 |
| 主办单位 | 合肥微尺度物质科学国家实验室，中科大化学与材料科学学院 |
| 报告介绍 | 报告摘要：
Our group as a longstanding interest in developing new methods for the synthesis of heterocycles, as well as the application of these methods to natural products total synthesis.1 Much work in our group has been directed towards heteroannulations of donor-acceptor cyclopropanes.2 In very general terms, if a species 1 contains orthogonally reactive nucleophilic and electrophilic sites, it may undergo reaction with cyclopropane 2 to yield intermediate 3.The stabilized anion in 3 may in turn react with the electrophilic site to form a cyclic product 4.This lecture will focus on the methodological aspects of our research with an emphasis on very recent results from our group. |
