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Plasmons under extreme dimensional confinement

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报告题目   Plasmons under extreme dimensional confinement
报告人   Prof. Hanno. H. Weitering
报告人单位   Department of Physics and Astronomy, University of Tennessee & Materials Science and Technology Division, Oak Ridge National Laboratory, USA
报告时间   2010-10-09
报告地点   合肥微尺度物质科学国家实验室一楼科技展厅
主办单位   合肥微尺度物质科学国家实验室
报告介绍
Plasmons are electronic density fluctuations inside a metal that usually resonate at ultraviolet frequencies. In our studies, we explore how surface and bulk plasmons emerge (or survive) under extreme dimensional confinement. Atomically-smooth ultrathin Mg films were epitaxially grown on Si(111), allowing for atomically-precise tuning of the bulk plasmon response and its bulk-sensitive probing via core-level photoemission. While the single-particle states in these 6-25 monolayer (ML) thick films consist of a series of two-dimensional subbands, the collective response is like that of a thin slice carved from bulk Mg subject to quantum-mechanical boundary conditions. Remarkably, this bulk-like behavior persists all the way down to five monatomic layers. In this low-dimensional crossover regime, plasmon modes are primarily excited via the sudden creation of the core hole as the extrinsic loss channel (which is the dominant channel in the bulk) is strongly suppressed. The collective response of the thinnest films is characterized by a thickness-dependent spectral weight transfer from the high-energy collective modes to the low-energy single-particle excitations, until the bulk plasmon ceases to exist below 5 ML. These results are striking manifestations of the role of quantum confinement on plasmon resonances in precisely controlled nanostructures. They furthermore suggest the intriguing possibility of tuning resonant plasmon frequencies via precise dimensional control.

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